两式HZSM-5用于Pickering乳液中的液体-液体接口的环烯水化
Changhao Bing1, Xubin Zhang1, Fumin Wang1
1School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P.R. China.
这项研究开发了两性HZSM-5热酸催化剂,以改善烯的水分. 修改后的焦化物增强了质量转移,抑制了副作用,显著提高了酒精产量.
科学领域:
- 催化剂是一种催化剂.
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 由于其表面积和酸性位点,石是有效的烯水化催化剂.
- 在传统的烯水化中,相位不混合性和以太化限制了酒精产量.
- 开发高效的催化剂用于烯水化仍然是一个关键的挑战.
研究的目的:
- 为了合成和表征两性HZSM-5热石,以增强烯水化.
- 为了研究在循环烯水化中修饰的化石的催化性能.
- 为了优化反应条件以最大限度地提高环醇产量.
主要方法:
- 化青石被硫化,以创建水油两性HZSM-5.
- 福利埃变换红外光谱学 (FT-IR),热重力测量分析 (TG) 和水接触角测量证实了成功的修改.
- 氨和的吸附红外光谱 (NH3-TPD和Py-IR) 分析了酸性部位.
- 使用两性烯酸催化剂进行了环二烯酸水合.
主要成果:
- 两式HZSM-5成功稳定了皮克林乳液,并在相位界面催化了反应.
- 硫化剂显著增加了强烈的布伦斯特酸位点的度.
- 环烯的转化率达到5.066%,对环醇的选择性为85.37%,接近反应平衡.
结论:
- 两性HZSM-5热是烯水化的一个有前途的催化剂,克服了相不混合性问题.
- 增强的布伦斯特德酸度和界面催化提高了酒精产量和选择性.
- 这种方法通过烯水化提供了一条更高效的酒精生产途径.
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