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Updated: Jul 10, 2025

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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基于的二变异性重组使得宝石异位基的三重功能化成为可能:一种不寻常的电化反应反应

Qiang Feng1, Chen-Xu Liu1, Qian Wang1

  • 1Laboratory of Synthesis and Natural Products (LSPN), Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne, EPFL-SB-ISIC-LSPN, BCH 304 1015, Lausanne, Switzerland.

Angewandte Chemie (International ed. in English)
|November 21, 2023
PubMed
概括

这项研究引入了一种新的催化反应,用于从碳酸盐酸中产生烯酸. 这种高效的方法在单个步骤中产生有价值的化化合物,具有多个新的键.

关键词:
1-甲基碳氧酸盐1 - 甲基碳氧酸盐双向性重组的重新安排化 化 化 化烯酸脱氧化法 烯酸脱氧化法高瓦伦特高瓦伦特

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Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...
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