合成半孔颗粒作为抑制剂容器用于抗腐蚀应用
Inime I Udoh1, Alicia G Garcia1, Kim Dam-Johansen1
1CoaST, Department of Chemical and Biochemical Engineering, Technical University of Denmark, Søltofts Plads, 2800 Kongens Lyngby, Denmark.
Langmuir : the ACS journal of surfaces and colloids
|November 21, 2023
概括
我们开发了一种新的,环保的方法,使用专门的装置来合成半孔颗粒 (MSP). 这种可扩展的技术允许高效,单封装本佐特醇 (BTA) 用于智能抗腐蚀涂层.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 化学工程是化学工程的重要组成部分.
背景情况:
- 半孔二氧化颗粒 (MSP) 是多功能材料,在药物输送和涂料中具有应用.
- 具有高封装效率的MSP的受控合成对于先进的应用至关重要.
- 现有的方法往往面临着可扩展性和环境影响方面的挑战.
研究的目的:
- 为MSP合成引入一种创新,环保和受控的实验组件.
- 为了证明抗腐蚀涂层的MSP中佐 (BTA) 的单封装.
- 为MSP生产建立一个可扩展和高效的实验室程序.
主要方法:
- 使用高速分散器和水循环器连接到双壁不钢容器.
- 采用修改后的Stöber方法进行MSP合成.
- 在颗粒形成过程中进行本佐特醇 (BTA) 的单封装.
主要成果:
- 成功合成了近球形和"豆形"MSPs (∼310 nm) 具有高BTA封装 (46 wt %).
- 在最佳条件下,通过23重%的BTA封装实现单分散球形MSP (∼1.1微米).
- 合成BTA封装的MSPs的pH响应性得到证明.
结论:
- 新型实验组件为环保MSP合成提供了可扩展和有效的途径.
- 一BTA封装产生了适合抗腐蚀涂层的智能纳米/微容器.
- 开发的方法提供了对粒子大小,形态和封装效率的增强控制.
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