在含有per-和多基物质的水性薄膜形成泡中寻找缺失的
Min Liu1, Caitlin M Glover1, Gabriel Munoz2
1Department of Civil Engineering, McGill University, Montreal, QC H3A 0C3, Canada.
Journal of hazardous materials
|November 21, 2023
概括
水性薄膜形成泡 (AFFFs) 是和多基基物质 (PFAS) 的重要来源. 这项研究在AFFF中确定了22个新的PFAS类,对于环境风险评估和补救策略至关重要.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
背景情况:
- 水性薄膜形成泡 (AFFF) 是对和多基物质 (PFAS) 的主要来源.
- 了解AFFF中的PFAS成分对于环境风险评估和有效补救至关重要.
研究的目的:
- 描述各种AFFF和非化泡中的PFAS类型和数量.
- 识别新的PFAS化合物,并比较PFAS量化的分析方法.
主要方法:
- 液体染色学与高分辨率质谱学 (LC-HRMS) 结合用于PFAS识别.
- 总氧化前体 (TOP) 测定和总有机 (TOF) 测量用于比较分析.
- 燃烧离子色谱 (CIC) 用于TOF测量.
主要成果:
- 非AFFF和无的泡含有很少或没有PFAS.
- 含有PFAS的AFFF表现出广泛的TOF度范围 (220045,000毫克F/L),并包含22个新的PFAS类.
- 虽然LC-HRMS有效量化了甲基 (FT) AFFF中的可氧化前体,但在电化学化 (ECF) AFFF中发现了重要的未知分数.
结论:
- LC-HRMS是识别新型PFAS和表征复杂泡混合物的强大工具.
- 接近质量平衡,突出了AFFF中以前未报告的PFAS的存在.
- 需要进一步的研究,以充分阐明ECF衍生的AFFF中PFAS的组成.
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