在纳米限制下地质体相互作用和放松动态:盐度和颗粒度的影响
Yuanzhong Zhang1, Rundong Huang1, Monica Iepure1
1Department of Chemical and Environmental Engineering, University of California, Riverside 92521 CA, USA.
Journal of colloid and interface science
|November 21, 2023
概括
在狭窄的地质空间中,纳米粒子的行为偏离了散装,特别是盐. 封闭,颗粒和离子度显著改变地质体的运输和质.
科学领域:
- 地质化学 地质化学
- 体科学 体科学 体科学
- 纳米技术纳米技术
背景情况:
- 与能源相关的污染物往往与地质聚合物有关.
- 地下裂中的地球体运输对于污染物分散至关重要.
- 了解纳米限制下的纳米粒子行为对于评估污染物运输至关重要.
研究的目的:
- 在纳米限制下研究纳米颗粒的界面行为.
- 为了确定水性介质条件如何影响纳米粒子动态.
- 为了测试这个假设,地质聚合物属性在被限制下偏离散体行为.
主要方法:
- 使用表面力装置来测量力形状和质性质.
- 研究了水性介质中的50纳米纳米粒子,这些纳米粒子被限制在表面之间.
- 不同的表面分离,颗粒度和盐度.
主要成果:
- 在临界表面分离时启动的非线性质行为.
- 在没有盐的情况下,纳米粒子悬浮物表现得像纯水一样.
- 盐的存在使得力概况和临界长度尺度对粒子度和束敏感.
- 观察到从牛顿式转变为剪切稀释行为,随着限制的增加.
结论:
- 束,粒子和离子度之间的相互作用改变了粒子间的力和学反应.
- 这些变化影响了纳米化体悬浮物在纳米限制下的运输行为.
- 这项研究为地质系统中地质体运输动态提供了新的见解.
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