在A15-Nb3Sn中,超导和电荷密度波动不稳定的共存
Li-Na Wu1, Si-Tong Yang1, Jin-Ke Shen1
1School of Sciences, Xi'an Technological University, Xi'an 710021, P. R. China.
Physical chemistry chemical physics : PCCP
|November 22, 2023
概括
在压力下研究了-锡 (Nb3Sn) 的超导性和结构不稳定性. 液压压力抑制电荷密度波 (CDW) 阶段,并影响超导过渡温度,揭示低压下共存.
科学领域:
- 凝聚物质物理学 凝聚物质物理学
- 材料科学 材料科学 材料科学
- 超导电性 超导电性 超导电性
背景情况:
- -锡 (Nb3Sn) 是一个关键的A15型超导体,具有高临界温度和电场.
- 了解其在压力下的行为对于先进的超导应用至关重要.
研究的目的:
- 研究水静压对Nb3Sn.结构不稳定性和超导性的影响.
- 确定压力如何影响电子属性,声子分散,电子-声子合和超导间隙.
主要方法:
- 使用第一原则计算来模拟Nb3Sn.
- 分析了电子特性,声子分散和电子-声子合.
- 在高达9 GPa的压力下计算了超导性能.
主要成果:
- 接近费米水平的范霍夫奇点表明了强大的电子 - 声子合.
- 声子分散中的科恩异常表明结构不稳定.
- 电荷密度波 (CDW) 不稳定性在6GPa以上消失.
- 在环境条件下超导过渡温度 (Tc) 为18.62K,与实验数据相匹配.
结论:
- 压力抑制了Nb3Sn.中的CDW阶段.
- 无论是CDW还是超导体,它们都依赖于压力,过渡温度下降至6GPa以下.
- 在压力超过6 GPa时,超导率会增加.
- Nb3Sn中的不稳定性与CDW和强大的电子-声波合驱动的声波模式软化有关,导致CDW和超导相在低压下共存.
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