准二维材料中的非平面铁电和强大的磁电
Xue-Zeng Lu1, Hui-Min Zhang1, Ying Zhou1
1Key Laboratory of Quantum Materials and Devices of Ministry of Education, School of Physics, Southeast University, Nanjing 211189, People's Republic of China.
Science advances
|November 22, 2023
概括
研究人员在薄膜中稳定了外平面铁电极纵向光学 (LO) 模式,克服了先进的存储器设备的去极化场,并使新的室温多重铁电成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 固态化学 固态化学
背景情况:
- 薄膜铁电材料对于电容和非易失性存储器件至关重要.
- 对于与半导体架构集成,需要外平面偏振.
- 超薄膜中的去极化场可以抑制所需的极化并增加功耗.
研究的目的:
- 研究在超薄膜中稳定平面外铁电的方法.
- 为了确定克服去极化场的机制.
- 设计用于电子应用的新型铁电和多铁材料.
主要方法:
- 用第一原则计算来研究极地模式的稳定性.
- 进行了对无三线模式合的分析.
- 结晶学耐受性因子被用来预测铁电.
主要成果:
- 在n=2 Ruddlesden-Popper家族中实现了极端纵向光学 (LO) 模式的稳定,从而实现了外平面铁电.
- 这种铁电在开放电路条件下持续存在,与超铁电不同.
- 稳定机制被发现在石灰和化物中无处不在.
- 一个晶体学耐受性因子被确定为外平面铁电的预测因子.
- 设计了一种具有强大的磁电合的室温多铁体.
结论:
- 发现的极性LO模式稳定提供了一条克服超薄铁电中去极化场的途径.
- 这项工作为低功耗,高性能非挥发性内存设备铺平了道路.
- 设计原理使得可以开发先进的多铁材料,用于磁电自旋轨道晶体管等应用.
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