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Updated: Jul 10, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
09:12

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

Published on: May 21, 2019

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铜-碳同解与精确定义的铜 (III) 复合物的减少消除相竞争

Wenhao Yan1, Samantha Carter2, Chi-Tien Hsieh3

  • 1Department of Chemistry, University of Cincinnati, Cincinnati, Ohio 45221, United States.

Journal of the American Chemical Society
|November 22, 2023
PubMed
概括

这项研究表明,-铜 (III) 复合物主要通过Cu-C同解分解,产生基和 (II) 种. 这些发现支持在铜催化反应中与铜的可逆重组.

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Lithium dialkyl cuprate, also known as Gilman reagents, selectively reduces acid halides to ketones. The acid chloride is treated with Gilman reagent at −78 °C in the presence of ether solution to produce a ketone in good yield.
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Birch reduction uses solvated electrons as reducing agents. The reaction converts benzene to 1,4-cyclohexadiene. The reaction proceeds by the transfer of a single electron to the ring to form a benzene radical anion. This anion is highly basic—it abstracts a proton from the alcohol to form a cyclohexadienyl radical. Another single electron transfer gives the cyclohexadienyl anion. A proton transfer from the alcohol forms 1,4-cyclohexadiene. Since this reduction occurs via radical anion...
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