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相关概念视频

Ionic Crystal Structures02:42

Ionic Crystal Structures

14.4K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.4K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.6K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.6K
Types Of Superconductors01:28

Types Of Superconductors

997
A superconductor is a substance that offers zero resistance to the electric current when it drops below a critical temperature. Zero resistance is not the only interesting phenomenon as materials reach their transition temperatures. A second effect is the exclusion of magnetic fields. This is known as the Meissner effect. A light, permanent magnet placed over a superconducting sample will levitate in a stable position above the superconductor. High-speed trains that levitate on strong...
997
Ionic Strength: Overview01:12

Ionic Strength: Overview

1.4K
The ionic strength of a solution is a quantitative way of expressing the total electrolyte concentration of a solution. This concept was first introduced in 1921 by two American physical chemists, Gilbert N. Lewis and Merle Randall, while describing the activity coefficient of strong electrolytes. During the calculation of ionic strength (I or μ), all the cations and anions are considered. However, the concentration (c) of an ion with a greater charge number (z) has a greater contribution...
1.4K
Ionic Strength: Effects on Chemical Equilibria01:19

Ionic Strength: Effects on Chemical Equilibria

1.5K
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
1.5K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

17.1K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Updated: Jul 10, 2025

Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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超离子导体的设计原则

Shuo Wang1, Jiamin Fu2,3, Yunsheng Liu1

  • 1Department of Materials Science and Engineering, University of Maryland, College Park, MD, 20742, USA.

Nature communications
|November 22, 2023
PubMed
概括
此摘要是机器生成的。

研究人员发现了新的超离子导体,用于可持续的电池. 一个关键的设计原则,面部共享站点,导致以化物为基础的材料具有创纪录的离子导电性.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 固态化学 固态化学

背景情况:

  • 高性能固态电池使用超离子导体.
  • 电池具有高能耗,低成本和可持续性的潜力.
  • 开发固态电池需要具有高离子导电性的超离子导体.

研究的目的:

  • 确定快速离子导体的设计原则.
  • 为了发现新的超离子导体材料.
  • 为了使先进的固态电池的发展.

主要方法:

  • 对离子和离子导体固体结构和扩散机制的比较研究.
  • 应用已识别的结构特征作为设计原则.
  • 对新发现的离子导体进行实验验证.

主要成果:

  • 揭示了面部共享高协调点作为快速离子导电的关键特征.
  • 在氧化物,硫化物和化物材料类中发现了多种新的离子导体.
  • 确定了一种基于的家族 (Na xM yCl 6,M = La-Sm),其UCL3型结构显示出报告中最高的离子导电性.

结论:

  • 快速离子导体材料的确立设计原则.
  • 为开发用于电池的优质离子导体铺平了道路.
  • 对于需要快速离子传输的各种能源应用,巩固了基本的理解.