可生物降解的乙胺用于逆阴离子漂浮,将超细石英从磁铁石分离出来
José Tadeu Gouvêa Junior1, Vitalis Chipakwe2, Laurindo de Salles Leal Filho3
1Department of Mining and Petroleum Engineering, Polytechnic School, University of São Paulo, Avenida Professor Melo Moraes, 2373, Cidade Universitária, São Paulo, SP, 05508-900, Brazil.
Scientific reports
|November 23, 2023
概括
可生物降解的胺有效地漂浮超细石英,将其与磁铁分开. 这些收集器通过聚合来增强磁石沉,改善矿物加工中的回收.
科学领域:
- 矿物加工和提取性金 矿物加工和提取性金
- 表面化学 表面化学
- 环境科学 环境科学
背景情况:
- 由于磁性分离效率下降,尾矿中的超细磁铁损失是一个重大问题.
- 阴离子逆漂浮为回收有价值的超细铁矿石颗粒提供了可行的替代方案.
- 开发环保试剂对于可持续的采矿业务至关重要.
研究的目的:
- 为了评估两个可生物降解的乙胺 (胺和单胺) 的浮动性能.
- 为了研究这些收集器,超细石英和磁铁之间的相互作用机制.
- 用这些新型试剂来确定石英与磁铁的分离潜力.
主要方法:
- 对超细颗粒 (<20微米) 进行单个和混合矿物浮动试验.
- 使用了包括泽塔电位,接触角度和表面张力测量的表面化学技术.
- 用光谱分析 (红外里叶变换) 和度测量来了解吸附和聚合现象.
主要成果:
- 乙胺和单胺都对超细石英表现出高漂浮效率 (分别为95.9%和97.7%).
- 实现了石英与磁铁的有效分离,这表明了收集器的选择性.
- 度数据表明收集器诱导的磁石聚合,促进其浮动中的沉降.
结论:
- 可生物降解的胺是超细石英漂浮的高效和选择性聚合物.
- 相互作用机制包括对石英的优先吸附和磁铁颗粒的聚合.
- 这些发现支持以太胺在可持续的超细磁回收过程中的应用.
更多相关视频
相关概念视频
Ion Exchange
595
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
595
Capillary Electrophoresis: Applications
402
Capillary electrophoretic separations offer various modes, each with unique applications. These modes include capillary zone electrophoresis, capillary gel electrophoresis, capillary array electrophoresis, capillary isoelectric focusing, capillary isotachophoresis, micellar electrokinetic chromatography, and capillary electrochromatography.
Capillary zone electrophoresis (CZE) separates ionic components based on their electrophoretic mobility. It has been used to separate proteins, amino acids,...
Capillary zone electrophoresis (CZE) separates ionic components based on their electrophoretic mobility. It has been used to separate proteins, amino acids,...
402
Ion-Exchange Chromatography
536
Ion-exchange chromatography, or IEC, is a technique for separating ions based on their affinity for the stationary phase. The stationary phase is a cross-linked polymer resin with covalently attached ionic functional groups. The functional groups can be either positively charged (cation exchangers) or negatively charged (anion exchangers). A cation exchanger consists of a polymeric anion and active cations, while an anion exchanger is a polymeric cation with active anions. The choice of...
536
Basicity of Heterocyclic Aromatic Amines
6.1K
Heterocyclic amines, where the N atom is a part of an alicyclic system, are similar in basicity to alkylamines. Interestingly, the heterocyclic amine having a nitrogen atom as part of an aromatic ring has much less basicity than its corresponding alicyclic counterpart. For this reason, as presented in Figure 1, piperidine (pKb = 2.8) is significantly more basic than pyridine (pKb = 8.8).
6.1K
Precipitation and Co-precipitation
1.8K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
1.8K


