寻找新型天然凝来改善大理石上的青铜液的清洁方法
Iñaki Vázquez-de la Fuente1, Inés Barbier1, Sara Puente-Muñoz1
1Department of Analytical Chemistry, Faculty of Science and Technology, University of the Basque Country UPV/EHU, P.O. Box 644, 48080 Bilbao, Basque Country, Spain.
Gels (Basel, Switzerland)
|November 24, 2023
概括
来自konjac和kudzu的新天然凝可以有效地从大理石遗产结构中去除铜污垢. 酸和葡萄酸是比EDTA更安全的合剂,可以防止大理石损伤.
科学领域:
- 材料科学 材料科学 材料科学
- 保护科学 保护科学
- 化学 化学 化学
背景情况:
- 大理石遗产结构易受铜漏的影响,导致绿色的斑点.
- 传统的清洁方法使用含有EDTA等结合剂的凝,可能会导致微生物生长和大理石损伤.
- 需要对遗产大理石进行有效和安全的清洁材料.
研究的目的:
- 评估康杰克和库祖凝作为阿加尔的替代品,用于从大理石中去除铜污点.
- 评估不同合剂 (EDTA,酸盐,氧酸盐,葡萄糖酸) 的疗效和合性.
主要方法:
- 用化剂添加的天然凝 (agar,konjac,kudzu) 的制备和应用.
- 使用色度测量,拉曼光谱,X射线光 (XRF) 和感应合等离子体质谱 (ICP-MS) 分析铜去除.
- 评估大理石表面的完整性和泄漏.
主要成果:
- 康杰克和库祖凝表现出有前途的清洁潜力,具有更简单的制备和固有的抗菌特性.
- 通过提取,EDTA显著损坏了大理石,而酸和葡萄糖酸显示出类似或更好的清洁性能,没有任何不良影响.
- 酸和葡萄糖酸被确定为安全有效的化剂,用于清除铜污垢.
结论:
- 康杰克和库祖凝与酸或葡萄糖酸相结合,是清除大理石遗产上的铜污点的安全有效替代品.
- 这些天然材料通过尽量减少对历史文物损坏,提供了改进的保护策略.
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