具有可定制的表面化学结构的化学稳定型 styrenic 电膜
Maura Sepesy1, Tuli Banik1, Joelle Scott1
1Department of Chemical and Biomolecular Engineering, Case Western Reserve University, Cleveland, OH 44106, USA.
Membranes
|November 24, 2023
概括
化学耐药的聚甲) 膜是使用电和交叉连接制造的. 这些膜具有很高的孔隙性和透性,在苛刻的溶剂和酸中保持完整性,用于先进的应用.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 膜的可定制表面化学性对于各种工业应用至关重要.
- 聚甲) 通过SN2化学或移植聚合提供了通过SN2化学或移植聚合的表面功能化的固有发起点.
- 电为制造具有可控形态的聚合物膜提供了一种方法.
研究的目的:
- 合成和表征化学耐药的聚甲基烯膜.
- 评估交叉连接在具有攻击性的化学环境中对膜稳定性的影响.
- 评估这些膜的潜力,作为一个平台技术,用于苛刻的分离过程.
主要方法:
- 通过电合成的多甲基 styrene) 膜.
- 在生产后使用胺进行交叉连接.
- 使用10M酸,乙醇和四基 (THF) 进行化学耐药性测试.
- 膜性质的表征,包括直径,多孔度和透度.
- 要素分析以大致估计交叉连接的程度.
主要成果:
- 电膜的直径为2-5微米,孔径超过80%.
- 高透度 (大约) 10,000 L/m2/h/bar) 在暴露于溶剂后得到维持.
- 交叉连接显著提高了化学稳定性,具有高度交叉连接的膜可以抵抗THF溶解.
- 元素分析表明交叉连接的程度在0.5到0.9N%之间.
结论:
- 交叉连接的聚甲膜显示出出色的化学耐受性和机械稳定性.
- 这些膜作为一个多功能平台技术,用于涉及有机溶剂,单体或强酸的应用.
- 可定制的表面化学结构使其能够进一步实现专门的分离任务的功能化.
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