对食品抗氧化化合物的结构能力的洞察力,使用胆量计进行评估
Francesco Siano1, Anna Sofia Sammarco2, Olga Fierro1
1Istituto di Scienze dell'Alimentazione, Consiglio Nazionale delle Ricerche, Via Roma 64, 83100 Avellino, Italy.
Antioxidants (Basel, Switzerland)
|November 25, 2023
概括
胆量计确定抗氧化能力 (CDAC) 提供了一种快速,准确的方法来测量食物中的抗氧化能力. 这项研究对48种常见的抗氧化剂进行了排名,揭示了它们的电化学反应和营养价值.
科学领域:
- 电化学 电化学 电化学
- 食品科学 食品科学 食品科学
- 分析化学 分析化学
背景情况:
- 抗氧化剂可以防止氧化应激.
- 量化抗氧化剂的能力对于食品科学和营养至关重要.
- 现有的方法可能在准确性或范围上有局限性.
研究的目的:
- 使用CDAC. 用于确定48种常见食品抗氧化剂的抗氧化能力.
- 建立基于电子转移的抗氧化能力的排名.
- 研究结构-活动关系并开发营养指数.
主要方法:
- 使用电生成 (Br2) 作为标称剂的恒流计.
- 用于终点确定的生物度检测.
- 摩尔比率CDAC (CDACχ) 和电化学比率 (ER) 的计算.
主要成果:
- CDAC提供了精确,灵敏,快速和经济高效的电子转移测量.
- 建立了抗氧化能力的清晰排名,酸,马尔维丁-3-O-葡萄糖酸和黄素显示高值.
- 观察到的黄类药物的排名并不总是与已建立的结构标准 (博尔斯标准) 保持一致.
结论:
- CDAC有效地估计了与的抗氧化反应的固态度系数.
- 这项研究为抗氧化剂结构与活性关系提供了宝贵的见解.
- 电化学比率 (ER) 提供了一个无维指数,用于在添加剂基础上估计食品的抗氧化能力.
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