增加三酸盐的水化活性,通过添加微分散的乙酸盐作为核剂
Yurii R Krivoborodov1, Svetlana V Samchenko1, Andrey V Korshunov1
1Department of Building Materials, Moscow State University of Civil Engineering, 26, Yaroslavskoye Shosse, 129337 Moscow, Russia.
Materials (Basel, Switzerland)
|November 25, 2023
概括
添加微分散乙酸到三酸 (C3S) 加快水化和硬化. 埃特林金石晶体充当核化位点,增强水酸盐的形成和增加强度,这对3D打印等建筑应用是有益的.
科学领域:
- 材料科学 材料科学 材料科学
- 土木工程 土木工程是指土木工程.
- 化学 化学 化学
背景情况:
- 三酸盐 (C3S) 是水泥和混凝土中的关键粘合剂,影响硬化和强度.
- 分散的添加剂可以微观地控制水化产品和水泥石结构的形成.
- 了解C3S水化动力学上的添加效应对于开发先进的水泥材料至关重要.
研究的目的:
- 为了研究微分散乙酸盐添加剂对三酸 (C3S) 的水化和硬化动力学的影响.
- 阐明矿在水酸盐的形成和生长中的作用.
- 评估矿对C3S基材料的定过程和机械性能的影响.
主要方法:
- 研究了矿对C3S水化动力学和热释放的影响.
- 使用电子显微镜观察化产品在矿表面的形成.
- 应用动力建模 (Avrami-Erofeyev模型) 来分析设置过程.
- 执行机械测量以评估修改样本的曲强度.
主要成果:
- 乙矿晶体选择性地吸附Ca2+和OH-离子,促进酸盐核的形成.
- 添加10%重量%的乙化石将诱导时间缩短了一半,并将早期水化热量增加15%.
- 电子显微镜揭示了在矿表面上显著形成水酸盐原子核.
- 动力建模表明,以石核化减缓,与对照样本加速核化形成鲜明对比.
- 青石作为水酸盐的核化中心,并作为强化填充剂,增加曲强度.
结论:
- 在C3S水化过程中,微分散性石作为水酸盐的预制核化中心.
- 乙矿增强了硬化过程,并增加了水泥石的曲强度.
- 这些发现支持使用矿用于控制水解和在水泥材料中形成结构,包括3D打印应用.
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