在波特兰水泥砂中通过表面电阻检测Cl-的透
Miguel Alberto Pablo-Calderón1, Prisciliano Felipe de Jesús Cano-Barrita1, Frank Manuel León-Martínez1
1CIIDIR Unidad Oaxaca, Instituto Politécnico Nacional, Calle Hornos No. 1003, Colonia Noche Buena, Sta. Cruz Xoxocotlán, Oaxaca 71230, Mexico.
Materials (Basel, Switzerland)
|November 25, 2023
概括
测量表面电阻,非破坏性地确定化物在水泥材料中的透深度. 这种方法与传统技术呈现出线性相关性,为材料评估提供了有前途的方法.
科学领域:
- 土木工程 土木工程是指土木工程.
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
背景情况:
- 表面电阻对水泥微观结构和孔隙溶液化学敏感.
- 化物进入会降解基于水泥的材料,影响耐用性.
- 非破坏性评估方法对于评估材料状况至关重要.
研究的目的:
- 使用Wenner阵列测量化物离子扩散引起的砂电阻变化.
- 通过电阻逆转确定的化物透深度与传统方法进行比较.
- 为了评估表面电阻作为化物透评估的非破坏性技术的有效性.
主要方法:
- 准备了各种组成 (普通波特兰水泥,飞灰) 和水/粘合剂比率的砂样本.
- 在175天内使用2.8M NaCl溶液诱导单向化物扩散.
- 化物透深度是使用银酸盐喷雾,电位计定位和电阻数据逆转 (RES1D软件) 来确定的.
主要成果:
- 从电阻逆转和传统方法中获得的化物透深度之间观察到一个线性关系 (R2 = 0.8612).
- 增加的化物度和透深度导致电阻率下降.
- 韦纳阵列使得化物透深度的非破坏性确定成为可能.
结论:
- 表面电阻的逆转是一种可行的非破坏性方法,用于量化化物透到基于水泥的材料.
- 这些发现支持使用电阻力来评估由于化物进入而导致的材料降解.
- 需要进一步的研究来验证这些研究结果在不同的环境条件下.
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