多壁碳纳米管剂量和超声波照射时间对水化热在水泥复合材料的演变的影响
Barbara Klemczak1, Eryk Goldmann1, Małgorzata Gołaszewska2
1Department of Structural Engineering, Faculty of Civil Engineering, Silesian University of Technology, 44-100 Gliwice, Poland.
Materials (Basel, Switzerland)
|November 25, 2023
概括
将多壁碳纳米管 (MWCNT) 添加到用超塑性化剂的水泥复合材料中,减少了早期的热释放和延迟的水合. 更高的MWCNT剂量和更长的超声波进一步降低了热量产生,并延长了这种延迟.
科学领域:
- 材料科学 材料科学 材料科学
- 土木工程 土木工程是指土木工程.
- 纳米技术纳米技术
背景情况:
- 水泥水化会产生热量,影响材料的性能和性能.
- 多壁碳纳米管 (MWCNTs) 正在探索用于增强水泥复合材料.
- 控制热量演变对于混凝土的耐用性和应用至关重要.
研究的目的:
- 调查MWCNTs对水泥水化过程中产生的热量的影响.
- 分析MWCNT剂量和超声波照射时间对水化动力学的影响.
- 了解超级可塑剂在MWCNT分散和热管理中的作用.
主要方法:
- 异热热量计用于测量168小时的累积热释放和热流量.
- 用不同的MWCNT剂量 (0.05-0.2重量%) 制备了水泥复合材料.
- 不同的超声波时间 (20分钟和60分钟) 适用于MWCNT分散.
主要成果:
- 带有乙烯基超塑性化剂的MWCNT减少了早期的热量排放,并延迟了加速周期.
- 增加MWCNT剂量降低了水合热的主要峰值速度.
- 较长的超声波时间导致更低的热量产生,减少主要峰值热速率,并延迟峰值发生.
结论:
- 当MWCNTs与超级塑化剂分散时,会显著改变水化水泥的热谱.
- 无论是MWCNT剂量和超声波参数都是影响水化动力学的关键因素.
- 优化MWCNT的结合可以帮助管理水泥材料中的热量产生.
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