填充化合物的墙壁无滑粘度的确定使用稳定状态剪切测量
Dennis Kleinschmidt1, Florian Brüning1, Jonas Petzke1
1Kunststofftechnik Polymer Engineering Paderborn, Faculty of Mechanical Engineering, Paderborn University, 33098 Paderborn, Germany.
Polymers
|November 25, 2023
概括
考克斯-梅尔兹规则不适用于用高压毛细管类风湿计 (HPCR) 测量的化合物. 闭腔风力计 (CCR) 方法提供准确的同热粘度数据,耗费较少的精力.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 类风病学 类风病学 类风病学
背景情况:
- 高压毛细管类风湿计 (HPCR) 用于塑料和的风湿性质.
- 化合物表现出流动异常和非异热效应,影响测量准确度.
- 现有的方法假定异热流和壁粘附,这在实践中经常被侵犯.
研究的目的:
- 通过使用HPCR来研究考克斯-默兹规则对化合物的适用性.
- 开发一种替代方法来准确测量化合物.
- 将新方法与现有技术进行比较.
主要方法:
- 研究了考克斯-默兹规则的经验性质转移函数.
- 使用了高压毛细血管风湿计 (HPCR) 和闭腔风湿计 (CCR).
- 在CCR中使用坡道测试开发了一种新的方法,用于墙壁无滑,异热数据收集.
主要成果:
- 对于未填充的EPDM或填充的化合物,无法验证Cox-Merz关系.
- 基于CCR的坡道测试方法产生了稳定状态剪切粘度数据.
- 生成的数据与修正的HPCR粘度数据有很高的一致性.
结论:
- 考克斯-梅尔兹规则不适用于化合物的学特征.
- 开发的CCR方法提供了准确的,同热的,无滑墙粘度数据.
- 对于化合物,CCR方法比传统的HPCR方法更有效.
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