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Updated: Jul 9, 2025

Utilization of Stop-flow Micro-tubing Reactors for the Development of Organic Transformations
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Utilization of Stop-flow Micro-tubing Reactors for the Development of Organic Transformations

Published on: January 4, 2018

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双甲和2,4-丁醇的基驱动转化:实验和计算分析

Jaya Das Schober1, Adam C Burdsall1, Troy Searcy1

  • 1Environmental Engineering and Science Program, Department of Systems Engineering and Management, Air Force Institute of Technology, Wright-Patterson AFB, Ohio, USA.

Water environment research : a research publication of the Water Environment Federation
|November 28, 2023
PubMed
概括

先进的氧化有效地从水中去除双A (BPA) 和2,4-丁二 (DNAN). 计算分析揭示了每个污染物的独特降解途径和能源需求,有助于水处理策略.

关键词:
2,4-丁氨基隔离剂的使用方法先进的氧化氧化方式.双 A 是一种双 A.密度函数理论密度函数理论反应机制的反应机制.水的质量水的质量.

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Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids

Diols are compounds with two hydroxyl groups. In addition to syn dihydroxylation, diols can also be synthesized through the process of anti dihydroxylation. The process involves treating an alkene with a peroxycarboxylic acid to form an epoxide. Epoxides are highly strained three-membered rings with oxygen and two carbons occupying the corners of an equilateral triangle. This step is followed by ring-opening of the epoxide in the presence of an aqueous acid to give a trans diol.
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All ortho–para directors, excluding halogens, are activating groups. These groups donate electrons to the ring, making the ring carbons electron-rich. Consequently, the reactivity of the aromatic ring towards electrophilic substitution increases. For instance, the nitration of anisole is about 10,000 times faster than the nitration of benzene. The electron-donating effect of the methoxy group in anisole activates the ortho and para positions on the ring and stabilizes the corresponding...
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A bond is formed between two atoms by sharing two electrons. When this bond is broken by supplying sufficient energy, either two electrons can be taken up by one atom forming ions by the cleavage called heterolysis, or the two electrons are shared by two atoms, with one each creating radicals by the cleavage called homolysis.
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