动态调节实现高性能含有La的普鲁士蓝色类似物用于水性K+存储
Fei Wang1, Xiaoyue Liu1, Jian Mao1
1College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China.
ACS applied materials & interfaces
|November 28, 2023
概括
含有兰的普鲁士蓝色类似物通过动态化学和结构调节实现稳定的水性离子储存. 这一策略克服了可溶性问题,提高了储能应用的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 无机化学 无机化学
背景情况:
- 兰 (La) 增强了材料性能,但含有La的普鲁士蓝色类似物 (PBA) 具有较差的水性稳定性.
- 在水性电解质中溶解La-PBAs限制了它们作为离子 (K+) 储存宿主的使用.
研究的目的:
- 制定一个动态的调节策略,以克服含有La的PBA的高溶解度.
- 为了实现高结构稳定性和优越的水性K+储存,使用含有La的PBA.
主要方法:
- 化学成分调节:Fe3+离子填充La3+空缺,修改表面以防止La溶解.
- 结构调节:在循环过程中从六角格子转变为立方格子,以获得最佳的结构.
- 电化学表征和密度函数理论 (DFT) 用于机制阐明.
主要成果:
- 修改后的表面有效地阻碍了原子溶解.
- 由于剩余的La原子,改善了电子/离子转移和增加了K+存储能力.
- 实现的超高容量:171 mAh g-1 在1 A g-1 时,稳定超过1000个周期.
结论:
- 一种新的动态调节策略成功地提高了含有La的PBA在水性电解质中的稳定性和K+储存性能.
- 开发的含有La的PBA显示出作为水性能量存储设备的先进阴极材料的巨大潜力.
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