短链水性有机硫酸盐气溶的物理特性
Alison Bain1, Man Nin Chan2,3, Bryan R Bzdek1
1School of Chemistry, University of Bristol Bristol UK b.bzdek@bristol.ac.uk.
概括
有机硫酸盐气溶对于气候建模至关重要. 这项研究测量了它们的物理性质,发现它们是盐和简单有机物之间的中间体,为气候预测提供了信息.
科学领域:
- 大气中的化学成分
- 环境科学环境科学
- 物理化学 物理化学
背景情况:
- 有机硫酸盐占气溶有机物质的很大一部分 (高达30%).
- 有机硫酸盐气溶的关键物理性质对于准确的气候建模至关重要,但人们对其了解甚少.
研究的目的:
- 测量和参数化水性有机硫酸盐溶液的物理性质.
- 将这些特性与盐和短链有机化合物进行比较,以评估近似潜力.
主要方法:
- 实验测量甲基和乙硫酸盐溶液的物理性质 (水活性,密度,折射率,表面张力).
- 数据的参数化作为溶液度的函数.
- 对有机硫酸盐,盐和有机分子的现有文献数据进行比较分析.
主要成果:
- 除了水活性外,有机硫酸盐的物理性质被发现是无机盐和短链有机化合物之间的中间体.
- 这表明有机硫酸盐不能直接通过更简单的分子对所有性质进行近似.
结论:
- 精确测量和建模大气中丰富的有机硫酸盐物理特性对于改善气候影响预测至关重要.
- 这些性质的中间性质需要具体的表征,而不是依赖于从更简单的化合物中获得的近似值.
相关概念视频
Structure and Nomenclature of Thiols and Sulfides
4.8K
Thiols and sulfides are sulfur analogs of alcohols and ethers, respectively, where the sulfur atom takes the place of the oxygen atom. Thus, thiols are generally represented as RSH, where R is an alkyl substituent and —SH is the functional group. On the other hand, in sulfides, the central sulfur atom is bonded to two hydrocarbon groups on either side. Depending upon the type of group, sulfides can be either symmetrical or asymmetrical. Both thiols and sulfides display a bent geometry,...
4.8K
Physical Properties of Carboxylic Acids
5.0K
Carboxylic acids with lower molecular weight exhibit a sharp and unpleasant odor. They also have higher boiling and melting points than analogous compounds, such as aldehydes, ketones, and alcohols.
5.0K
Preparation and Reactions of Sulfides
4.8K
Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
4.8K
Colloids
17.5K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.5K
Solubility
17.5K
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
17.5K
Physical Properties Affecting Solubility
22.7K
Solutions of Gases in Liquids
As for any solution, the solubility of a gas in a liquid is affected by the attractive intermolecular forces between solute and solvent species. Unlike solid and liquid solutes, however, there is no solute-solute intermolecular attraction to overcome when a gaseous solute dissolves in a liquid solvent since the atoms or molecules comprising a gas are far separated and experience negligible interactions. Consequently, solute-solvent interactions are the sole...
As for any solution, the solubility of a gas in a liquid is affected by the attractive intermolecular forces between solute and solvent species. Unlike solid and liquid solutes, however, there is no solute-solute intermolecular attraction to overcome when a gaseous solute dissolves in a liquid solvent since the atoms or molecules comprising a gas are far separated and experience negligible interactions. Consequently, solute-solvent interactions are the sole...
22.7K


