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来自一种芳香的生物基基架的高性能聚胺玻璃

Kevin A Stewart1, Jacob J Lessard1, Alexander J Cantor1

  • 1George & Josephine Butler Polymer Research Laboratory, Center for Macromolecular Science & Engineering, Department of Chemistry, University of Florida Gainesville Florida 32611 USA sumerlin@chem.ufl.edu.

RSC applied polymers
|November 28, 2023
PubMed
概括

来自素的生物基玻璃剂为高性能热保护提供了可持续的解决方案. 这些可回收和可再生材料具有出色的热稳定性和机械再加工性,可用于先进的应用.

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Ring-opening metathesis polymerization or ROMP involves strained cycloalkenes as starting materials. The mechanism of ROMP proceeds by reacting cycloalkene with Grubbs catalyst to give metallacyclobutane intermediate which undergoes a ring-opening reaction to form new carbene. The new carbene reacts with another molecule of cycloalkene. Repetition of these steps leads to the formation of an unsaturated open-chain polymer product. All these steps are reversible, however, relieving the ring...
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