新的高发光红色发射复合物:合成,表征,Judd-Ofelt强度参数和药理学研究
Manoj Kumar1, Vaishnavi Lather2, Poonam Nandal3
1University Institute of Engineering and Technology, Maharshi Dayanand University, Rohtak, , 124001, India.
Journal of fluorescence
|November 28, 2023
概括
新的红色发光欧欧 (((III) 复合物使用β-基联体和类衍生物进行了合成. 这些复合物表现出有前途的抗微生物和抗氧化活性,以及显著的光发光特性.
科学领域:
- 协调化学 协调化学
- 材料科学 材料科学 材料科学
- 光物理学的光学物理学
背景情况:
- 欧洲 (III) 复合物以其发光特性而闻名.
- 开发新的配体对于调整这些特性至关重要.
- 与光学特性一起研究药理活动提供了多功能应用.
研究的目的:
- 合成和描述新的红色发光欧欧 (III) 复合物.
- 评估光发光特性,包括Judd-Ofelt参数和量子效率.
- 评估合成化合物的抗菌和抗氧化潜力.
主要方法:
- 复杂合成的溶液沉方法.
- 使用元素分析,FT-IR和1H-NMR进行表征.
- 光发光谱学,紫外线分析和计算方法.
- 通过管稀释方法的抗微生物活性和通过DPPH测定的抗氧化活性.
主要成果:
- 成功合成了新型红色发光Eu(III) 复合物与CHDME和phenanthroline辅助配体.
- 详细的表征证实了复合体的结构和纯度.
- 确定了Judd-Ofelt参数 (Ω2, Ω4),发光量效率 (η) 和光带间隙.
- 基CHDME及其Eu(III) 复合物表现出显著的抗微生物和抗氧化活性.
结论:
- 合成的Eu(III) 复合物具有可取的光发光特性.
- 这些复合体显示出在材料科学和药物化学中的应用潜力.
- 该研究突出了影响发光和生物活动的结构属性关系.
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