强烈耐热的改水性聚氨/聚胺压力敏感粘合剂
Hangzhou Wang1,2, Xiaobin Li1,2, Ending Zhang1,2
1Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, People's Republic of China.
Langmuir : the ACS journal of surfaces and colloids
|November 28, 2023
概括
一种新型的改水性聚氨/聚胺压力敏感粘合剂 (WPUPSA) 显示了增强的热稳定性和优越的粘合性能. 这一发展显著提高了高温应用中的性能,提供了更大的强度和耐用性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
背景情况:
- 水性聚氨压力敏感粘合剂 (WPUPSAs) 提供环保优势,但热稳定性不佳.
- 高温应用需要具有更好的耐热性和强大的机械性能的粘合剂.
研究的目的:
- 开发一种新型的改性,耐热水性聚氨/聚胺压力敏感粘合剂 (WPUPSA).
- 为了提高WPUPSA的耐热性和粘合性,用于高温应用.
主要方法:
- 用三位交联剂将水性聚氨 (WPU) 改造成网络结构.
- 通过 pyromellitic dianhydride (PMDA) 和 isophorone diisocyanate (IPDI) 的反应将伊米德和环纳入WPU骨干.
主要成果:
- 热耐受性指数增加了15.2%.
- 在室温180°下,剥离强度和剪切阻力分别提高了80.9%和231.8%.
- 与未经修改的样本相比,在80°C和100°C时观察到增强的剥离强度和剪切阻力.
结论:
- 开发的改性WPUPSA显示了显著改善的热稳定性和粘合性能.
- 网络结构和imide环的结合有效地增强了凝聚力的能量和耐热性.
- 这种材料显示出用于高温压力敏感粘合剂应用的巨大潜力.
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