垃圾填埋污水中的自然和人为溶解有机物:组成,转化及其共存特征
Jing Zheng1, Xian-Ge Wang2, Yue Sun2
1State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China; State Environmental Protection Key Laboratory of Simulation and Control of Groundwater Pollution, Chinese Research Academy of Environmental Sciences, Beijing 100012, China; College of Environmental Science and Engineering, Guilin University of Technology, Guilin 541000, China.
Journal of hazardous materials
|November 28, 2023
概括
垃圾填埋场液含有自然和人造溶解有机物 (DOM). 人类DOM随着时间的推移而增加,慢慢降解和积累,而自然DOM转变和减少,影响垃圾填埋场的组成.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 分析化学 分析化学
背景情况:
- 垃圾填埋场从自然和人为废物中产生溶解有机物 (DOM).
- 在液中DOM的组成和转化尚未完全理解.
研究的目的:
- 为了全面描述垃圾填埋场中的自然和人为DOM.
- 研究DOM在填埋过程中的转化和共存.
主要方法:
- 里叶变换离子循环子子共振质谱法 (FT-ICR-MS)
- 尺寸排除色谱 (SEC) 是一种尺寸排除色谱.
- 气色谱 - 质谱学 (GC-MS) 气色谱
- 3D激发发射矩阵 (EEM) 光谱学
主要成果:
- 自然DOM在较旧的液中减少,直链有机酸消失,蛋白质和湿性物质前体显著减少.
- 人类DOM增加,在较旧的液中占主导地位,其中含有诸如芳香酸和化有机物等化合物.
- 人类DOM的降解速度比自然DOM慢,导致积累. 自然DOM有助于一些化合物的脱.
结论:
- 垃圾填埋改变了浸出物DOM的组成,增加了性物质和化有机化合物.
- 缩的液循环加剧了这些化合物的积累.
- 了解DOM动态对于填埋场管理和环境影响评估至关重要.
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