实时in situ监测使用可见光谱仪作为探测电化学先进氧化过程的工具,用于染料脱色
Chelsea M Schroeder1, Taylor M Koehler1, Kristiane K Ohlhorst1
1Department of Chemistry, University of Connecticut 55 North Eagleville Road Storrs Connecticut 06269 USA nicholas.leadbeater@uconn.edu.
RSC advances
|November 29, 2023
概括
使用活性硫酸盐的优化电化学方法有效地去色染料,优于阳极氧化. 染料结构显著影响脱色率,这对于废水整治策略至关重要.
科学领域:
- 环境化学环境化学
- 电化学 电化学 电化学
- 分析化学 分析化学
背景情况:
- 废水处理需要有效的染料脱色方法.
- 电化学过程为污染物降解提供了有前途的解决方案.
- 紫外线可见光谱仪可实时监测化学反应.
研究的目的:
- 为了优化电化学活性硫酸盐用于染料脱色.
- 为了将这种方法与各种染料类的阳极氧化进行比较.
- 为了研究染料结构对降解速率的影响.
主要方法:
- 实时现场监测使用紫外线可见光谱光度计.
- 优化电极组合,电流密度,硫酸盐负载和速度.
- 对电化学激活的硫酸盐和氧化对,三甲和桑染料的比较分析.
主要成果:
- 电极组成,电流密度,硫酸盐负载和速度影响色化率.
- 亚和桑染料的降解速度比三甲染料要快.
- 提取电子的组和素对变色速度产生了负面影响.
- 与阳极氧化相比,电解活性硫酸盐显示出更好的脱色,特别是在缺乏电子的染料中.
结论:
- 硫酸盐的电化学激活是染料脱色的有效方法.
- 染料的分子结构是决定降解效率的关键因素.
- 这项研究为设计电化学废水处理过程提供了必要的数据.
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