聚刷涂料用于循环:移植,退化和重复生长
Maria Brió Pérez1, Mark A Hempenius1, Sissi de Beer1
1Sustainable Polymer Chemistry Group, Department of Molecules & Materials, MESA+ Institute for Nanotechnology, Faculty of Science and Technology, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands.
Macromolecules
|November 29, 2023
概括
研究人员开发了可降解的聚合物刷,使用表面启动的环开放聚合. 这些聚涂层在降解后可以在基板上重新生长,为永久性聚合物刷提供了可持续的替代品.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 表面工程是什么?表面工程是什么?
背景情况:
- 聚合物刷对于表面修改至关重要,但通常使用非生物降解材料,导致塑料废物.
- 现有的聚合物刷缺乏可控的降解和基板可重复使用性.
研究的目的:
- 开发一种用于移植可降解聚合物刷的合成策略.
- 为了实现对基板的聚合物刷子的受控水解和再生.
- 为不可降解的聚合物刷提供可持续的替代品.
主要方法:
- 有机催化表面启动的环开放聚合 (SI-ROP).
- 来自基于PGMA的宏观发起者的聚刷 (PLA,PCL,PHB).
- 在各种pH溶液和海水中通过厚度变化监测降解.
主要成果:
- 实现了高达50纳米厚的聚刷涂层.
- 在所有测试的溶液中,PHB刷子迅速降解.
- PLA和PCL刷子显示稳定性高达pH 8;所有在海水中在14天内降解.
- 经过降解后,在相同的基板上显示了刷子的再生.
结论:
- 通过SI-ROP开发了一种通过SI-ROP创建可调节,可降解的聚刷的方法.
- 这些刷子提供受控的降解,并使基板可重复使用.
- 为传统的不可降解的聚合物刷提供了一个有希望的,环保的替代品.
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