水对中等等级煤的有效孔结构的影响:基于预冷吸附-脱实验
Zhixuan Li1, Ke Wang1, Yi Lou2
1College of Resources and Environmental Engineering, Guizhou University, Guiyang 550025, China.
ACS omega
|November 29, 2023
概括
随着湿度的上升,煤矿孔中的水从单层转移到凝结,影响甲的储存. 这项研究揭示了水如何影响煤炭.
科学领域:
- 煤炭地质学和水库工程
- 多孔的媒体科学科学.
- 吸附科学是一种吸附科学.
背景情况:
- 水的存在显著影响煤炭储库中甲的有效孔隙空间.
- 了解煤孔中的水吸附对于优化甲回收和储存至关重要.
研究的目的:
- 在不同尺度上研究煤炭孔内的水吸附行为.
- 阐明不同孔径大小的水的分布特征.
- 揭示吸附水对煤矿孔隙结构和甲储存能力的影响.
主要方法:
- 结合湿度平衡和预冷的吸附-溶解实验.
- 分析不同相对湿度 (RH) 的水蒸气吸附机制.
- 评估特定表面积和毛孔体积的变化,以增加水分含量.
主要成果:
- 水蒸气吸附过渡从单层到多层到凝结随着RH的增加.
- 吸附水显著降低了吸附能力,特定表面积和有效毛孔体积,特别是在小于10纳米的毛孔中.
- 增加的水分含量会改变吸附-脱吸曲线的分支点,表明孔壁光滑性和结构复杂性的变化.
结论:
- 煤孔中的水的出现和吸附是由相对湿度和孔径大小决定的.
- 吸附的水显然改变了煤炭的孔隙结构,影响了煤炭储存甲的能力.
- 这些发现为煤床甲储库中的水岩相互作用提供了关键的见解.
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