从皮和枣中提取的TiO2修饰活性碳从水中吸附铜:响应表面方法优化
Roya Sadat Neisan1, Noori M Cata Saady1, Carlos Bazan2
1Department of Civil Engineering, Faculty of Engineering and Applied Science, Memorial University of Newfoundland, St. John's, NL, A1B 3X5, Canada.
Heliyon
|November 29, 2023
概括
从皮和枣种子中改造的活性碳,增强了二氧化纳米颗粒,有效地从水中去除铜离子. 这种环保吸附剂具有高的去除率和容量,为净化水提供了可持续的解决方案.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 水处理 处理水的方法
背景情况:
- 水生环境中的铜 (Cu) 污染带来了重大风险.
- 对于重金属而言,传统的水处理方法可能昂贵且低效.
- 来自农业废物的活性炭提供了可持续的吸附剂前体.
研究的目的:
- 为了评估从皮 (OP) 和枣种子 (DS) 中修饰活性炭 (AC) 的铜离子去除效率.
- 调查二氧化纳米颗粒 (TiO2 NPs) 修饰对交流特性和吸附性能的影响.
- 使用响应表面方法 (RSM) 来优化吸附条件.
主要方法:
- 来自皮 (AC-OP) 和枣种子 (AC-DS) 的活性炭被合成.
- AC-OP和AC-DS被修改为TiO2NP,其重量比例为1:10%.
- 使用RSM与中央复合设计 (CCD) 进行批量吸附实验,以优化pH值,初始度,吸附剂剂量和接触时间.
主要成果:
- TiO2 NP修改显著增加了AC-OP和AC-DS的表面积.
- 确定了TiO2修饰AC-OP (OP-TiO2) 和AC-DS (DS-TiO2) 的最佳条件,实现了高的Cu去除效率 (分别为99.90%和97.40%).
- 伪二次运动模型最好地描述了吸附过程,表明化学吸附.
结论:
- 来自皮和枣的TiO2-修饰活性碳是铜离子的高效吸附剂.
- 该研究表明,农业废弃物衍生材料在环境修复方面得到了成功的应用.
- 这些发现为开发高效和可持续的吸附剂提供了宝贵的见解,用于从水中去除重金属.
相关概念视频
Extraction: Advanced Methods
450
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
450
Precipitation and Co-precipitation
1.8K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
1.8K
Electrodeposition
639
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Electrodeposition can...
639


