在化青混凝土混合物中对6PPD-金的研究
Srinidhi Lokesh1, Siththarththan Arunthavabalan1, Elie Hajj1
1Department of Civil and Environmental Engineering, University of Nevada, Reno, 1644 N. Virginia Street, Reno, Nevada 89557, United States.
ACS environmental Au
|November 29, 2023
概括
轮胎化学物质6PPD- (6PPD-Q) 对鱼有毒. 化青混合物吸收了6PPD-Q,保留了它并释放了最小量的流水,这表明了对这种新出现的污染物的潜在缓解策略.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 生态毒理学 生态毒理学
背景情况:
- 它的副产品6PPD- (6PPD-Q) 通过城市风暴排水在鱼中引起急性毒性.
- 青混凝土 (AC) 表面,通常含有回收轮胎 (RTR),是6PPD-Q从轮胎释放的主要接口.
研究的目的:
- 通过化青混合物研究6PPD-Q的吸附和脱附.
- 在模拟降雨期间,从压缩青中量化6PPD-Q的调动.
主要方法:
- 使用压缩和粉碎的松散化青混合物进行了吸附和脱附实验.
- 使用降雨模拟实验来测量6PPD-Q的下水度.
主要成果:
- 对于6PPD-Q,在12天内达到吸附平衡,吸附系数为151.57-257.51L/kg,用于压缩混合物.
- 6PPD-Q的溶解率很低,在水中的度在0.01-0.09μg/L之间.
- 6PPD-Q的排水度明显低于鱼和斑马鱼幼虫的致命水平.
结论:
- 化青混合物有效吸收并保留6PPD-Q,作为这种轮胎衍生污染物的沉池.
- 从正在使用的交流表面释放的6PPD-Q是最小的,这表明道路上的轮胎磨损颗粒对水生生态系统的风险降低了.
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