选择性减少氧气的单原子催化剂:在高负荷的统一碳纳米圈中的过渡金属
Jacob Jeskey1, Yong Ding2, Yidan Chen2
1School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332, United States.
JACS Au
|November 30, 2023
概括
一种新的单方法简化了在碳纳米圈中创建过渡金属单原子催化剂 (SAC). 这种方法产生了高度活性和选择性的电催化剂,包括用于氧降解反应 (ORR) 的基于铁的SAC.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 催化剂是一种催化剂.
背景情况:
- 过渡金属单原子催化剂 (SAC) 为电催化提供低成本,高活性和选择性.
- 目前生产SAC的方法往往是复杂的多步骤过程,不适合工业扩展.
研究的目的:
- 开发一种简单的单方法,以在均的碳纳米圈中合成过渡金属SAC.
- 证明该方法在各种过渡金属中的多功能性及其在氧降解反应 (ORR) 中的应用.
主要方法:
- 使用乙烯基胺四酸 (EDTA) 作为分子屏障的化学限制策略被采用.
- 这种方法抑制了纳米粒子的形成,使得原子隔离金属原子的高负载成为可能.
- 合成了Fe,Co,Cu和Ni的SAC,负载高达3.87%的重量.
主要成果:
- 合成的基于Fe的SAC显示出出色的ORR活性,其起始和半波潜力为1.00和0.831V$_{RHE}$,与商业Pt/C相比.
- 可以通过改变过渡金属来调整ORR的选择性,将其导向能源产生或过氧化生产.
结论:
- 已经建立了一个简单的,无模板的,单方法,用于在碳纳米圈中生产高负载过渡金属SAC.
- 开发的SAC显示了高的催化性能和ORR的可调性选择性,显示了电化学应用的巨大潜力.
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