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对于TATB的新热分解途径

Keith D Morrison1, Ana Racoveanu2, Jason S Moore3

  • 1Lawrence Livermore National Laboratory, Nuclear and Chemical Sciences Division, Livermore, CA, 94550, USA.

Scientific reports
|December 1, 2023
PubMed
概括

1,3,5-triamino-2,4,6-trinitrobenzene (TATB) 的热分解开始于环分解,产生CO2. 这一发现影响了高能材料的安全模型.

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Sigmatropic rearrangements are a class of pericyclic reactions in which a σ bond migrates from one part of a π system to another. These are intramolecular rearrangements where the total number of σ and π bonds remain unchanged.
Sigmatropic shifts are classified based on an order term [i, j ], where i and j indicate the number of atoms across which each end of the σ bond migrates. Below are examples of a [3,3] sigmatropic shift in...
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