Jove
Visualize
联系我们
JoVE
x logofacebook logolinkedin logoyoutube logo
关于 JoVE
概览领导团队博客JoVE 帮助中心
作者
出版流程编辑委员会范围与政策同行评审常见问题投稿
图书馆员
用户评价订阅访问资源图书馆顾问委员会常见问题
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experiments存档
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教师资源中心教师网站
使用条款与条件
隐私政策
政策

相关概念视频

Catalysis02:50

Catalysis

27.0K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
27.0K
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

3.3K
Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
3.3K
Crystal Growth: Principles of Crystallization01:25

Crystal Growth: Principles of Crystallization

2.0K
Crystallization is a phase transformation process in which crystals are precipitated from a supersaturated solution or formed from other sources. During crystallization, atoms or molecules arrange themselves into a well-defined, rigid crystal lattice to minimize energy.
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
2.0K
Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation02:24

Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

7.7K
Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
7.7K
Reduction of Alkenes: Catalytic Hydrogenation02:13

Reduction of Alkenes: Catalytic Hydrogenation

12.1K
Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
12.1K
Recrystallization: Solid–Solution Equilibria01:10

Recrystallization: Solid–Solution Equilibria

1.1K
Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
1.1K

您也可能阅读

相关文章

通过共同作者、期刊和引用图与本文相关的文章。

排序
Same author

Gas-Solid van der Waals Interaction Driving the Dynamic Evolution of Surface Nanostructures.

Journal of the American Chemical Society·2026
Same author

From Single Motif to Active Ensembles: Phase-Controlled Co<sub>8</sub> Cluster Catalysis on MoS<sub>2</sub> for Nitrogen Electroreduction.

Advanced materials (Deerfield Beach, Fla.)·2026
Same author

Orchestrating structure and chemistry dynamics for cluster catalysis.

National science review·2026
Same author

Strong Metal-Metal Interaction-Induced Encapsulation of Cobalt by Lanthanum Nitride for Efficient Ammonia Synthesis.

Journal of the American Chemical Society·2026
Same author

Electron-Rich Subnanometer Cu Clusters Facilitate CO-CO Coupling in CO<sub>2</sub> Electroreduction.

Journal of the American Chemical Society·2026
Same author

Nature of Reverse Water-Gas Shift Reactions at Metal-Oxide Interfaces Uncovered via Interpretable Machine Learning.

Journal of the American Chemical Society·2026
Same journal

Synthetic Porous Carbons for High-Energy, High-Power Supercapacitors.

Chemical reviews·2026
Same journal

Navigating Misfolded Terrain: ER-Associated Degradation of Membrane Proteins.

Chemical reviews·2026
Same journal

Ink Design for Printing Perovskite Solar Cells and Modules.

Chemical reviews·2026
Same journal

Advanced Single-Atom Catalysts for Thermal-Catalytic C1 Chemistry.

Chemical reviews·2026
Same journal

Copper-Dependent Polysaccharide Monooxygenases: Mechanism and Function.

Chemical reviews·2026
Same journal

To Biotic or Abiotic: Biohybrid Systems for Artificial Photosynthesis.

Chemical reviews·2026
查看所有相关文章

相关实验视频

Updated: Jul 9, 2025

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
08:25

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs

Published on: January 17, 2020

7.3K

晶相工程在异质催化中的工程.

Jian-Wen Zhao1, Hong-Yue Wang1, Li Feng1

  • 1Key Laboratory of Precision and Intelligent Chemistry, School of Chemistry and Materials Science, iChem, University of Science and Technology of China, Hefei, Anhui 230026, China.

Chemical reviews
|December 4, 2023
PubMed
概括
此摘要是机器生成的。

在异质催化剂中的催化剂性能取决于电子和几何结构. 晶相工程提供了一种策略,通过控制原子排列和表面特征来优化催化剂,以提高活性和选择性.

更多相关视频

Multiscale Sampling of a Heterogeneous Water/Metal Catalyst Interface using Density Functional Theory and Force-Field Molecular Dynamics
10:52

Multiscale Sampling of a Heterogeneous Water/Metal Catalyst Interface using Density Functional Theory and Force-Field Molecular Dynamics

Published on: April 12, 2019

12.8K
Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
12:08

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

Published on: June 24, 2022

3.5K

相关实验视频

Last Updated: Jul 9, 2025

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
08:25

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs

Published on: January 17, 2020

7.3K
Multiscale Sampling of a Heterogeneous Water/Metal Catalyst Interface using Density Functional Theory and Force-Field Molecular Dynamics
10:52

Multiscale Sampling of a Heterogeneous Water/Metal Catalyst Interface using Density Functional Theory and Force-Field Molecular Dynamics

Published on: April 12, 2019

12.8K
Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
12:08

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

Published on: June 24, 2022

3.5K

科学领域:

  • 材料科学 材料科学 材料科学
  • 化学工程是化学工程的重要组成部分.
  • 催化剂是一种催化剂.

背景情况:

  • 不同质的催化性能依赖于材料的电子和几何结构.
  • 萨巴蒂埃原理指导着通过组合诱导的电子结构修改来引导催化剂设计.
  • 催化剂表面特征 (梯田,边缘,台阶) 显著影响反应活性和选择性.

研究的目的:

  • 审查催化性能在异质催化中对晶相的依赖性.
  • 阐明在分子层面上理解催化剂-晶相关系的挑战.
  • 通过晶相工程,为改善催化剂设计提供见解.

主要方法:

  • 审查现有的关于催化过程中的晶相工程的文献.
  • 分析几何原子结构对催化活性和选择性的影响.
  • 评估分子层面的洞察力,对不同晶相的活性部位进行评估.

主要成果:

  • 晶相工程改变了电子和几何配置,影响了协调数和表面原子排列.
  • 调节晶体相是提高催化剂稳定性,活性和选择性的关键.
  • 目前缺乏对晶相间活性位点的全面分子层次的理解.

结论:

  • 了解结晶相效应对于推进异质催化是至关重要的.
  • 晶相工程为优化催化剂性能提供了一个强大的策略.
  • 需要进行进一步的研究,以弥合针对性催化剂设计的活性位点在分子层面上的理解差距.