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溶解物扩散与动态粘度的相关性在添加盐 (胆化物+甘油) 的深度环氧溶剂中
Manish Kumar1, Siddharth Pandey1
1Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi - 110016, India. sipandey@chemistry.iitd.ac.in.
Physical chemistry chemical physics : PCCP
|December 4, 2023
概括
含有LiCl的深溶解溶剂 (DES) 显示了由动态粘度而不是微异质性控制的溶解物扩散. 这项研究强调了DES作为溶解物中的多功能介质,其中粘度决定了扩散动态.
科学领域:
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
背景情况:
- 深度浸泡溶剂 (DES) 具有有利的物理化学特性,推动它们在化学中被采用.
- 在电化学应用中,添加金属盐的DES被探索为有机电解质的替代品.
- 了解这些系统中的溶液扩散对于优化它们的性能至关重要.
研究的目的:
- 为了研究在添加LiCl的深度欧性溶剂 (甘油) 中溶解物扩散动态.
- 评估温度和LiCl度对转化和旋转扩散的影响.
- 为了确定扩散和溶剂的动态粘度之间的关系.
主要方法:
- 在转化扩散研究中利用烯-甲作为光灭器对.
- 使用烯作为光异型旋转器用于旋转扩散测量.
- 分析了光火和重定向时间,以确定扩散系数和粘度依赖.
主要成果:
- 由双分子火速常数 (k_q) 量化的转化扩散遵循斯托克斯-爱因斯坦关系,表明粘度控制.
- 旋转重定位时间 (θ) 也随着动态粘度而变大,并遵循斯托克斯-爱因斯坦关系.
- 发现微/纳米异质性对溶液扩散动态的影响很小.
结论:
- 在添加LiCl的甘氨酸中溶液的扩散主要由溶液的动态粘度决定.
- DESs提供了一个介质,其中扩散动态仅仅是由粘度决定的.
- 该研究确定了动态粘度在这些先进的溶剂系统中控制翻译和旋转扩散的作用.
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