通过对III组元素进行兴奋剂来规范磁铁的和磁化
Yanying Ren1, Yaning Li2, Nan Xu1
1The Second Hospital of Dalian Medical University, Dalian 116024, China. chenxincjz@gmail.com.
Physical chemistry chemical physics : PCCP
|December 4, 2023
概括
将氧化铁纳米颗粒与和相配合可以增强它们的磁性. 这一改进对于推进纳米医学的应用至关重要,例如向药物输送和磁性高温治疗.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 计算化学的计算化学
背景情况:
- 磁铁氧化物 (Fe3O4) 纳米粒子对于纳米医学应用至关重要.
- 合成Fe3O4纳米颗粒中的低和磁化 (MS) 限制了它们在药物输送和磁性高温症中的使用.
- 需要策略来增强Fe3O4纳米颗粒的磁性.
研究的目的:
- 为了研究Fe3O4纳米粒子中的III组元素 (Al,Ga,In) 的兴奋剂行为.
- 评估兴奋剂对Fe3O4.4的磁性和电子性质的影响.
- 确定增加Fe3O4纳米粒子和磁化 (MS) 的方法.
主要方法:
- 使用了精确的混合密度函数计算.
- 研究了Fe3O4中的Al,Ga和In元素的兴奋剂行为.
- 分析了与兴奋剂度相关的磁性和电子性质.
主要成果:
- 兴奋剂的行为取决于兴奋剂的度.
- 适当的度的Ga和In兴奋剂显著增加Fe3O4.4的和磁化 (MS).
- 用Al,Ga和In进行兴奋剂不会在带间隙中引入缺陷状态,而是稍微增加它.
结论:
- 通过III组元素兴奋剂确定了一种可行的方法来增强磁铁纳米颗粒的MS.
- Ga 和 In 兴奋剂为改善 Fe3O4 纳米粒子性能提供了一个有前途的途径.
- 增强的Fe3O4纳米粒子对于推进药物输送和磁性高温应用具有重要意义.
更多相关视频
10:45Stable Aqueous Suspensions of Manganese Ferrite Clusters with Tunable Nanoscale Dimension and Composition
Published on: February 5, 2022
4.3K
06:53Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
2.0K
相关概念视频
Colors and Magnetism
11.7K
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
11.7K
Ferromagnetism
2.4K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
2.4K
Valence Bond Theory
8.6K
Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
8.6K
Magnetic Moment of an Electron
1.4K
Electrons revolving around a nucleus are analogous to a circular current carrying loop. This current produces a magnetic dipole moment proportional to the electron's orbital angular momentum. Since the orbital angular momentum is quantized in terms of the reduced Planck's constant, the dipole moment is quantized in the Bohr Magneton. The value of the Bohr magneton is 9.27 x 10-24 Am2. Electrons also have an intrinsic spin angular momentum, and the associated spin magnetic moment is...
1.4K
Properties of Transition Metals
26.0K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
26.0K
