多面体的寡合性西尔斯基奥克桑D3h-(RSiO1.5) 14) 它们是多面体
Marc Hunsicker1, Ankur1, Bernd Morgenstern2
1Krupp-Chair of General and Inorganic Chemistry, Saarland University, 66123, Saarbrücken, Germany.
Chemistry (Weinheim an der Bergstrasse, Germany)
|December 6, 2023
概括
研究人员开发了一种简单的方法来合成更大的多面体寡合性丝素 (POSS) . 这一突破为T14Ph14 POSS结构提供了高收益率,这是迄今为止最大的特征.
科学领域:
- 材料科学 材料科学 材料科学
- 有机化学 有机化学
- 纳米技术 纳米技术
背景情况:
- 具有n>12的较大的多面体寡合性丝素 (POSS) 难以合成和认证.
- 对于较大的POSS系统,现有的方法是漫长的,产量低.
研究的目的:
- 展示一个特定的大型POSS的简单高收益的合成.
- 用有机替代剂对最大的结晶学认证POSS进行表征.
主要方法:
- 用催化三甲硫酸对T7Ph7(OH) 3丝素进行处理.
- 在晶体形式的T14Ph14框架的隔离.
- 使用单晶X射线衍射,多核核核磁共振和热分析进行分析.
- 密度函数理论 (DFT) 方法用于确定异构体能量.
主要成果:
- 取得了令人惊的简单和高收益的访问替代D3h对称的T14同位素 (T14Ph14).
- 成功地将最大的POSS (T14Ph14) 与有机替代剂隔离和特征化.
- 使用DFT.确定所有四种可能的T14Ph14异构体的相对能量.
结论:
- 开发的方法为更大的POSS结构提供了一条有效的途径.
- 这项工作扩大了用于高级应用程序的可访问POSS的范围.
- 这些发现有助于进一步研究大型POSS系统的特性和应用.
相关概念视频
Hybridization of Atomic Orbitals II
32.3K
sp3d and sp3d 2 Hybridization
32.3K
Ionic Crystal Structures
14.4K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.4K
Hybridization of Atomic Orbitals I
47.1K
The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...
47.1K
Preparation and Reactions of Sulfides
4.8K
Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
4.8K
VSEPR Theory and the Basic Shapes
68.4K
Overview of VSEPR Theory
68.4K


