对于高功率密度质子交换膜燃料电池在微孔层的接口上调节运输
Ningran Wu1, Ye Liu2, Shengping Zhang1
1National Key Laboratory of Advanced Micro and Nano Manufacture Technology, School of Integrated Circuits, Peking University, Beijing, 100871, China; Beijing Advanced Innovation Center for Integrated Circuits, Beijing, 100871, China; Academy for Advanced Interdisciplinary Studies, Peking University, Beijing, 100871, China; Technology Innovation Center of Graphene Metrology and Standardization for State Market Regulation, Beijing Graphene Institute, Beijing 100095, China.
研究人员通过在微孔层 (MPL) 中使用纳米多孔石墨烯改进了质子交换膜 (PEM) 燃料电池. 这提高了功率密度,并减少了用于可持续能源的质量运输阻力.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 可持续能源 可持续能源
背景情况:
- 质子交换膜 (PEM) 燃料电池提供可持续的能源转换.
- 微孔层 (MPL) 在PEM燃料电池中管理气体和水的运输.
- 传统的MPL限制功率密度由于欧姆和质量传输损失.
研究的目的:
- 通过优化MPL材料来提高PEM燃料电池功率密度.
- 为了减轻MPL-催化剂层接口上的质量传输损失.
- 研究石墨烯作为MPL中碳黑的替代品.
主要方法:
- 评估了两种类型的石墨烯作为MPL材料.
- 评估了石墨烯的电子导电性和与水的界面特性.
- 研究了纳米多孔石墨烯促进的快速水蒸发.
- 量化功率密度和质量传输阻力.
主要成果:
- 基于石墨烯的MPL显著提高了功率密度,达到1.1W cm−2.2.
- 与碳黑MPL相比,大规模运输阻力降低了75%.
- 在各种湿度条件下表现出更好的性能.
结论:
- 纳米孔状石墨烯是下一代PEM燃料电池MPL的一个有希望的材料.
- 石墨烯的加入有效地解决了PEM燃料电池中的运输限制.
- 结果为燃料电池应用中的合体系统中控制界面质量传输提供了洞察力.
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