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从具有高气体吸收率的活性冰中增强甲酸盐的形成
Peng Xiao1, Juan-Juan Li1, Wan Chen1
1State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing, 102249, P. R. China.
Nature communications
|December 6, 2023
概括
活性冰是一种带有未冷表面活性剂层的多孔冰,可极大地加速气体水合物形成,以有效地储存和分离气体. 这种创新材料为工业应用提供了可持续和经济的解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 储能 储能 储能 储能 储能 储能
背景情况:
- 气体水合物为气体储存,运输和分离提供了有前途的解决方案.
- 克拉酸的形成速度缓慢,阻碍了它们的商业可行性.
研究的目的:
- 开发一种名为"活性冰"的新材料,可显著加速气酸盐的形成.
- 解决传统的基于水合物的天然气管理技术的局限性.
主要方法:
- 通过低剂量二甲硫酸盐 (SDS) 形成气酸盐并随后在冰点以下解离,产生活性冰.
- 通过将冰粉或雪与SDS混合进行替代制备.
- 气体储存容量和在甲吸收过程中释放的热量的表征.
主要成果:
- 活性冰加快了气体水合物形成,产生了最小的热量.
- 达到了高达185VgVw-1的高气体储存容量,释放的热量为~18kJmol-1CH4.
- 通过低于冰点的压缩来证明活性冰的轻松再生,使周期性相变成为可能.
结论:
- 活性冰提供了一种绿色,经济和高效的气体储存和分离方法.
- 活性冰的循环性克服了基于水合物的技术的关键缺点.
- 这种方法为天然气酸盐技术的工业应用铺平了道路.
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