通过多聚电解质刷形成的表面固定互聚电解质复合体
Artem M Rumyantsev1, Ekaterina B Zhulina2, Oleg V Borisov2,3
1Department of Chemical and Biomolecular Engineering, North Carolina State University, Raleigh, North Carolina 27695-7905, United States.
ACS macro letters
|December 7, 2023
概括
对比释放驱动了聚电解质刷和相反电荷的聚合物之间的复杂形成. 这项研究开发了一种介聚电解质协复合物 (IPEC) 形成的理论,揭示了集群形成和相位分离的条件.
科学领域:
- 聚合物科学 聚合物科学
- 软物质物理学 软物质物理学
- 物理化学 物理化学
背景情况:
- 聚电解质 (PE) 刷子在表面修饰和纳米技术中广泛使用.
- 了解PE刷和移动聚合物之间的相互作用对于设计先进材料至关重要.
研究的目的:
- 在平面聚电解质刷和相反电荷的移动线性聚合物之间形成复杂的缩放理论.
- 研究这些系统的驱动力,结构过渡和相位行为.
主要方法:
- 理论缩放分析. 理论缩放分析.
- 聚合物刷形状和相互作用的建模.
- 热力学驱动力的分析,包括反离子释放.
主要成果:
- 抗体释放被确定为复杂化的主要驱动因素.
- 介聚电解质协复合体 (IPEC) 的形成发生在中等接种密度和低盐度下.
- 更高的接种密度导致移动链透,刷结构由弹性和短距离力控制.
- 盐度增加导致客聚离子释放.
- 微相分离和有限大小的IPEC集群形成预测适度的接种密度,并确定了电力法依赖性.
结论:
- 开发的理论为理解PE刷/线性PE复杂化提供了一个框架.
- 预测IPEC形成的条件,结构过渡和表面诱导的相位分离.
- 通过接种密度,聚合物长度和盐度来控制材料特性.
相关概念视频
Protein-protein Interfaces
12.5K
Many proteins form complexes to carry out their functions, making protein-protein interactions (PPIs) essential for an organism's survival. Most PPIs are stabilized by numerous weak noncovalent chemical forces. The physical shape of the interfaces determines the way two proteins interact. Many globular proteins have closely-matching shapes on their surfaces, which form a large number of weak bonds. Additionally, many PPIs occur between two helices or between a surface cleft and a...
12.5K
Ion Exchange
594
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
594
Intermolecular Forces
58.4K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
58.4K
Interfacial Electrochemical Methods: Overview
251
Interfacial electrochemical methods focus on the phenomena occurring at the boundary between an electrode and a solution, as opposed to bulk methods that concentrate on the solution's overall properties. These interfacial methods are classified as either static or dynamic based on the presence of a nonzero current in the electrochemical cell and the consistency of analyte concentrations. Static methods, such as potentiometry, measure the cell's potential without any significant current...
251
Solubility
17.5K
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
17.5K


