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一种基于胆的抗复合剂,对Zn-Br流电池具有选择性兼容性.
Ming Zhao1,2, Tao Cheng1,2, Tianyu Li1
1Division of Energy Storage, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhongshan Road 457, Dalian, 116023, China.
Small (Weinheim an der Bergstrasse, Germany)
|December 8, 2023
概括
一种新的基于胆的复合剂 (CCA) 在低温下有效地在-流电池 (Zn-Br2 FBs) 中液化聚化物. 这一创新使得电池性能稳定,持久,即使在零度以下的条件下.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 聚化物的高结点阻碍了-流电池 (Zn-Br2 FB) 的发展.
- 开发有效的低温电解质对于扩大FB应用至关重要.
研究的目的:
- 设计一种基于胆的复合剂 (CCA),以克服Zn-Br2 FB中的聚胺结问题.
- 为了提高Zn-Br2 FBs的低温性能和循环寿命.
主要方法:
- 合成了一种基于胆的复合剂 (CCA) 与N-甲基-N-乙基-盐 (CCA-M).
- 研究了CCA-M与聚胺离子的复合.
- 在各种温度下使用CCA-M评估Zn-Br2 FBs的电化学性能.
主要成果:
- 该CCA-M有效地液化了聚化物,保持液态至-40°C.
- 具有CCA-M的Zn-Br2FBs在-20°C下显示出延长的循环寿命 (>150个循环) 和高的库伦比效率 (≈98.8%).
- 在室温下,电池实现了超过1200个循环,具有≈94.7%的库伦比效率.
结论:
- 开发的CCA-M是一种高效的防剂,用于Zn-Br2 FBs中的聚化物.
- 这种方法显著提高了低温电池性能和循环稳定性.
- 在其他低温基储能系统中,CCA-M显示出更广泛的应用潜力.
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