提高伊特里亚稳定合金复合材料的性能,使用化伊米达酸框架衍生的纳米碳素
Niyaz Cakan1, Abduselam Abubeker Issa1, Hamza Alsalman2
1Department of Materials Science and Engineering, Faculty of Engineering, Eskisehir Technical University, Eskisehir 26555, Turkey.
ACS applied materials & interfaces
|December 9, 2023
概括
金属有机框架 (MOF) 衍生的纳米碳显著增强陶基质复合材料 (CMC). 这项研究表明,在用ZIF-67衍生纳米碳化合物增强的伊特里亚稳定 (YSZ) 中,破裂性和导电性得到改善.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 陶工程 陶工程
背景情况:
- 陶矩阵复合材料 (CMCs) 对于增强的机械,热和电性能具有兴趣.
- 石墨烯和碳纳米管是常见的纳米碳添加剂,但CMC中的金属有机框架 (MOF) 衍生的纳米碳是未被充分探索的.
研究的目的:
- 研究MOF衍生的纳米碳化合物的有效性,作为替代陶基质中的强化阶段.
- 探索ZIF-67衍生纳米碳对伊特里亚稳定 (YSZ) 性能的影响.
主要方法:
- 使用火花等离子烧结 (SPS) 巩固了YSZ和热带石化伊米达酸框架 (ZIF-67) 粉末混合物.
- 复合材料在1300°C和50MPa下烧结,ZIF-67作为纳米碳源.
主要成果:
- 与单体YSZ相比,由于ZIF衍生的纳米碳层间层,断裂性增加了高达13%.
- 室温电导率达到27S/m,重量10%为ZIF-67,归因于in situ纳米碳填充剂.
- 纳米碳中间层促进了能量消散,抑制了谷物生长,增强了柔性.
结论:
- 在CMC中在现场将MOF衍生的纳米碳化合物纳入,可以显著改善机械和电气性能.
- 由ZIF-67衍生出的纳米碳提供了一个有前途的途径,用于先进的CMC开发.
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