拉曼光谱法对石相关石墨的石墨等价评估
Wubo Chu1,2, Wen Dai1, Bo Wang1,3
1Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China.
Materials (Basel, Switzerland)
|December 9, 2023
概括
本研究介绍了一种拉曼光谱法,用于量化石相关石墨中的石墨含量. 开发的技术准确地评估了各种工业应用的石墨资源.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 分析化学 分析化学
背景情况:
- 炭石相关的石墨是一种有价值的资源,除了燃料之外还有各种应用.
- 精确量化石墨含量对于资源评估和利用至关重要.
研究的目的:
- 开发和验证一种方法来评估使用拉曼光谱的石墨等价的石墨.
- 为这种重要的碳材料建立可靠的定量分析技术.
主要方法:
- 准备带有已知石墨度的石墨-石英标准样本.
- 使用拉曼光谱仪获取拉曼光谱.
- 对D和G峰的峰值适配分析以提取光谱参数 (位置,强度比,半宽,面积).
- 基于峰值面积数据的标准曲线和合适方程的开发.
主要成果:
- 与石墨含量相关的拉曼光谱参数 (D和G峰) 的趋势被确定.
- 建立了一个标准曲线和配合方程,具有很高的合适度 (R2 = 0.9984).
- 开发的方法已成功应用于评估100个自然样本中的石墨含量.
结论:
- 拉曼光谱,特别是D和G峰值分析,提供了一种可靠的方法,用于对石墨同等价值的评估.
- 已建立的定量方法为评估这一重要的石墨资源提供了可靠的工具.
相关概念视频
Raman Spectroscopy: Overview
407
The underlying principle of Raman spectroscopy is based on the interaction between light and matter, specifically molecules' inelastic scattering of photons. When a monochromatic beam of light, typically from a laser source, interacts with a sample, most scattered light has the same frequency as the incident light. This is known as Rayleigh scattering.
However, a small fraction of the scattered light exhibits a frequency shift due to the exchange of energy between the incident photons and...
However, a small fraction of the scattered light exhibits a frequency shift due to the exchange of energy between the incident photons and...
407
Raman Spectroscopy Instrumentation: Overview
428
A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector.
The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...
The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...
428
Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview
382
Attenuated total reflectance (ATR) infrared spectroscopy is a powerful analytical technique used to study the composition of materials. It is widely employed in chemistry, materials science, forensic science, and other fields where sample characterization is required. ATR has several advantages over traditional transmission IR spectroscopy, including the requirement of little to no sample preparation and the ability to analyze a wide range of samples.
The ATR process begins by directing a beam...
The ATR process begins by directing a beam...
382


