同时193nm的能力 - LIBS/LA-ICP-MS成像用于微塑料的表征
Lukas Brunnbauer1, Mara Jirku1, C Derrick Quarles2
1TU Wien, Institute of Chemical Technologies and Analytics, Getreidemarkt 9/164-I2AC, 1060, Vienna, Austria.
Talanta
|December 9, 2023
概括
本研究引入了一种用于微塑料分析的新型LIBS/LA-ICP-MS方法. 它准确地识别了聚合物类型,包括化化合物,并量化了单个微塑料颗粒中的金属含量.
科学领域:
- 环境科学 环境科学
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
背景情况:
- 微塑料 (MP) 构成了重大环境挑战,需要先进的监测和分析.
- 包括聚合物类型和金属含量在内的MP的特征对于了解其环境命运和影响至关重要.
- 来自化聚合物的和多醇基物质 (PFAS) 特别令人担忧,因为它们对环境产生严重影响.
研究的目的:
- 为了证明同时进行激光诱导分解光谱 (LIBS) 和激光剥离-诱导合等离子体质谱 (LA-ICP-MS) 设置用于微塑料分析.
- 展示LIBS在微塑料中成像和识别含聚合物的能力.
- 通过LIBS和ICP-MS的结合方法,对单个微塑料中的金属含量进行定量分析.
主要方法:
- 在同时使用LIBS/LA-ICP-MS仪器进行微塑料分析.
- 采用5微米斑点大小和ICCD检测的目标LIBS,用于成像和识别含聚合物.
- 聚合物分类的联合LIBS与ICP-MS用于金属量化,使用50微米点尺寸和宽带光谱仪.
主要成果:
- 使用LIBS.证明成功成像和识别微塑料中的含聚合物.
- 实现了对单个微塑料中的金属含量进行矩阵匹配的量化.
- 使用ICP-MS.同时使用0.72μg/g的 (Pb) 和9.5μg/g的锡 (Sn) 的确定的检测极限.
结论:
- 开发的同时LIBS/LA-ICP-MS设置对于全面的微塑料表征是有效的.
- 该方法允许精确识别聚合物类型和量化微塑料中的金属污染物.
- 该技术为环境监测和微塑料污染风险评估提供了一个强大的工具.
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