一个高精度和广泛的pH监测系统,基于宽带空洞增强的吸收频谱
Anqi Yang1, Yan Huang2, Songbao Fu3
1Centre for Optical and Electromagnetic Research, National Engineering Research Center for Optical Instruments, Zhejiang Provincial Key Laboratory for Sensing Technologies, Zhejiang University, Hangzhou 310058, China; Interdisciplinary Student Training Platform for Marine Areas, Zhejiang University, Hangzhou 310027, China.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
|December 9, 2023
概括
一种新型的高精度pH监测系统采用腔增强和二进制指示膜,用于在广泛的pH范围 (-0.3到14.3) 中进行准确的测量. 这种技术非常适合恶劣的环境.
科学领域:
- 分析化学 分析化学
- 频谱学是一种光谱学.
- 化学传感器 化学传感器
背景情况:
- 精确的pH监测在各种环境和工业应用中至关重要.
- 现有的方法可能受到范围,准确性或在具有挑战性的条件下稳定的限制.
研究的目的:
- 开发一种高精度的pH监测系统,其检测范围扩大,准确度提高.
- 为了利用空腔增强和先进的光谱分析来获得更好的pH传感.
主要方法:
- 一个带有二进制指示膜 (刚果红色和m-cresol紫色) 的微流体芯片被集成到一个空腔增强模块中.
- 一个超频谱传输模块记录了频谱,转换为宽带空腔增强吸收频谱 (BBCEAS).
- 人工神经网络 (ANN) 用于pH预测.
主要成果:
- 该系统显示了从pH值-0.3到14.3的广泛检测范围,响应时间为120秒.
- 洞穴增强显著提高了准确性,从0.137降低根平均平方误差 (RMSE) 到0.073.
- 该系统显示出出色的重复性,长期稳定性,离子电阻和有机耐腐蚀性.
结论:
- 拟议的空腔增强的超谱pH监测系统提供了高精度和广泛的检测范围.
- 它的坚固性能使其适用于海水监测和工业废水分析等苛刻的应用.
相关概念视频
Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation
230
Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
There are three main types of inductively coupled plasma atomic emission spectroscopy (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used....
There are three main types of inductively coupled plasma atomic emission spectroscopy (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used....
230
Atomic Absorption Spectroscopy: Instrumentation
745
An atomic absorption spectrophotometer (AAS) comprises several components: a radiation source, an atomizer, a monochromator, and a detector. The radiation source can be a hollow-cathode lamp (HCL) or an electrodeless-discharge lamp (EDL), both of which provide a narrow emission line of the required wavelength. However, some instruments use continuum sources and high-resolution monochromators to achieve a narrow range of radiation.
The atomizer used in AAS can be either a flame atomizer or an...
The atomizer used in AAS can be either a flame atomizer or an...
745
UV–Vis Spectrometers
1.3K
The absorbance of UV and visible (UV–visible) radiations is measured using a UV–visible spectrophotometer. Deuterium lamps, which emit UV radiation, and tungsten lamps, which produce radiation in the visible region, are used as light sources in UV–visible spectrophotometers. A monochromator or prism is used for diffraction grating, i.e., to split the incoming radiation into different wavelengths. A system of slits is used to focus the desired wavelength on the sample cell.
1.3K
Atomic Emission Spectroscopy: Lab
167
AES is a powerful analytical technique, especially effective when used with plasma sources, producing abundant spectra in characteristic emission lines. The Inductively Coupled Plasma (ICP), in particular, yields superior quantitative analytical data due to its high stability, low noise, low background, and minimal interferences under optimal experimental conditions. However, newer air-operated microwave sources are emerging as promising alternatives that could be more cost-effective than...
167
Raman Spectroscopy Instrumentation: Overview
428
A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector.
The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...
The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...
428


