一个热球结构分离器,用于高度安全的离子电池
Mengning Luo1, Xueqian Zhang2, Sen Wang1
1School of Chemistry & Chemical Engineering, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei, 230601, China.
Small (Weinheim an der Bergstrasse, Germany)
|December 10, 2023
概括
一种新的聚乙烯化物/聚胺 (PVDF/PEI) 分离器通过防止热失控,提高了电池的安全性. 这种高热稳定性的分离器在高温下有效地阻断离子流,提高了电池的性能和在滥用条件下安全.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 商用聚烯烯分离器的热稳定性较差,增加了电池热失控的风险.
- 分离器对于离子传输和防止电池中电极短路至关重要.
研究的目的:
- 开发一种热稳定的分离器,以提高电池的安全性.
- 研究离子电池中新型PVDF/PEI分离器的性能和安全性.
主要方法:
- 用分散的PEI微球制造一个PVDF/PEI分离器.
- 在200°C进行热稳定性测试和在150°C进行离子阻断评估.
- LiNi0.6Co0.2Mn0.2O2/Li电池的电化学循环和袋式电池上的指甲透测试.
主要成果:
- 在200°C时,PVDF/PEI分离器呈现罕见的收缩,在150°C时阻断了离子传输.
- 在80°C的100个循环后,LiNi0.6Co0.2Mn0.2O2/Li电池显示96.5%的容量保留.
- 囊细胞通过了无烟无火的指甲透测试,表明安全性有所提高.
结论:
- 与商业分离器相比,开发的PVDF/PEI分离器提供了优越的热稳定性和安全特性.
- 这种分离器设计有效地减轻了离子电池中的热失控风险.
- 这种材料对更安全,更持久的储能应用具有前景.
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