使用高玻璃过渡温度的1,6-hexanediamine获得的聚乙烯2,5-furandicarboxylate) 共聚乙烯
Ying Wang1,2, Kunmei Su2, Chengzhi Liu3
1State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International Joint Research on Separation Membranes, Tiangong University Tianjin 300387 China.
RSC advances
|December 11, 2023
概括
基于的新型聚胺表现出改善的热和机械性能. 这些材料还表现出增强的紫外线可降解性和染料拒绝应用的潜力.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 有机合成 有机合成
背景情况:
- 基于的聚合物为以石油为基础的塑料提供了可持续的替代品.
- 聚胺 (聚胺) 结合了聚和聚胺的理想特性.
- 通过单体替代调整聚合物特性是材料设计中的一个关键策略.
研究的目的:
- 通过结合胺链接,合成基于的新型聚胺.
- 为了研究胺合并对热,机械和降解性能的影响.
- 探索在染料排斥技术中的潜在应用.
主要方法:
- 通过对1,4-butanediol与hexamethylene diamine的部分替代,合成聚乙烯2,5-酸盐-协同乙烯 furanamide (PBAF).
- 使用玻璃过渡温度 (Tg) 测量的热性质的表征.
- 评估机械性能,包括拉伸模量和强度.
- 评估紫外线可降解性和染料排斥性能.
主要成果:
- 已经成功地合成了PBAF聚合物,其和胺单元的比例不同.
- 在PBA20F中,Tg显著增加 (约. 50%) 和改善的拉伸性能.
- 随着胺含量增加,观察到增强的紫外线吸收和可降解性.
- 对于染料排斥应用得到了有希望的结果.
结论:
- 用六甲二胺部分替代有效地提高了基于的聚胺的热和机械稳定性.
- 胺键的结合提高了紫外线可降解性,为可光降解材料提供了潜力.
- 这些新型聚胺显示出先进应用的前景,包括水处理和染料去除.
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