通过SSVG和MBE方法生长的Pb1-CdTe晶体的纳米硬度和Young的模量
Wojciech Wołkanowicz1, Stanisław Adamiak2, Anna Juś2
1Institute of Physics, Polish Academy of Sciences, al. Lotników 32/46, 02-668 Warsaw, Poland.
ACS omega
|December 11, 2023
概括
这项研究研究了基化 (PbCdTe) 晶体的机械性能. 使用自选蒸汽增长 (SSVG) 方法培养的PbCdTe晶体显示硬度增加,含量更高.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 晶体学 晶体学是指结晶学.
背景情况:
- Telluride (PbTe) 是一个有前途的热电材料.
- 将 (Cd) 纳入PbTe可以调整其电子和光学特性.
- 了解PbCdTe合金的机械性能对于设备制造和性能至关重要.
研究的目的:
- 研究PbCdTe单晶和MBE培养层的纳米硬度和扬斯模量.
- 为了比较通过自我选择蒸汽增长 (SSVG) 和分子束表 (MBE) 制备的PbCdTe的机械性能.
- 阐明Cd度,晶体结构和机械行为之间的关系.
主要方法:
- 纳米印技术用于测量纳米硬度和模量.
- 奥利弗和法尔的方法来计算机械性能.
- 通过SSVG和MBE培养的层培养的PbCdTe单晶的分析.
主要成果:
- 在SSVG培养的PbCdTe晶体中观察到显著的硬化,其Cd含量增加.
- 在MBE培养的固体溶液中确定了2.1%的CdTe可溶性极限,在更高度下没有检测到沉物.
- 在SSVG和MBE样本之间,在弹性变形能量和模量方面发现了显著的差异.
- 证明了子子网外的Cd原子增加了纳米硬度.
- 观察到的效应归因于MBE层中较高的点缺陷度,特别是间歇性Cd-Te空位复合体.
结论:
- Cd的结合显著影响了PbCdTe的纳米硬度和Young的模量.
- 在类似的Cd度下,SSVG方法产生的晶体与MBE培养的层相比,具有较低的异质性和更高的硬度.
- 缺陷点度,特别是间歇性Cd-Te空置复合体,在MBE培养的PbCdTe中在硬化机制和位移动态中发挥着关键作用.
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