圆柱形单基炮推进剂化反应过程的动态模型
Fan Cui1, Hong-Lei Fan1, Shi-Ying Li2
1School of Chemistry and Chemical Engineering, North University of China, Taiyuan 030051, China.
ACS omega
|December 11, 2023
概括
通过控制脱反应动力学来制备度分布推进剂 (NGDP). 该研究揭示了试剂度如何影响反应控制,影响推进剂燃烧的渐进性,以获得最佳的能量释放.
科学领域:
- 推进剂化学 推进剂化学
- 化学动力学 化学动力学
- 材料科学 材料科学 材料科学
背景情况:
- 基梯度分布推进剂 (NGDP) 提供逐渐释放的能量.
- 表面功能组 (-O-NO2) 通过脱反应进行改变.
- 反应动力学极大地影响酸盐的分布和燃烧特性.
研究的目的:
- 为了研究圆柱形单基炮推进剂的脱反应的动力模型.
- 了解化试剂度如何影响反应动力学和控制机制.
- 为控制的NGDP准备提供理论指导.
主要方法:
- 使用收缩无反应核心 (SUC) 模型进行动力分析.
- 通过测量推进剂颗粒中的能量变化,评估了脱率.
- 将实验数据与拟议的SUC圆柱形模型相匹配.
主要成果:
- 化反应的控制取决于度.
- 在6%的试剂度下,观察到化学反应控制 (Ea = 48.40 kJ·mol−1).
- 在15%的试剂度下,固体产品层扩散控制占主导地位 (Ea = 84.77 kJ·mol−1).
结论:
- 动力模型阐明了NGDP的脱过程.
- 控制试剂度是定制推进剂燃烧渐进性的关键.
- 结果支持NGDP的发展,具有可预测的能量释放特征.
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