二 (硫) 胺为结合二氧酸盐电极上的稳定介面
Hao Wu1, Wenfang Feng1, Michel Armand2
1Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan 430074, China.
ACS applied materials & interfaces
|December 11, 2023
概括
二 (fluorosulfonyl) 胺 (LiFSI) 电解盐通过形成稳定的固体-电解质-间相 (SEI) 层来改善甲 (LiTPA) 电池的性能. 这提高了可持续的高能电池的循环和速率性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 碳基负电极,如甲酸盐 (LiTPA),为可充电电池提供高能量密度和可持续性.
- 固体电解质介相 (SEI) 层质量差目前限制了LiTPA电极的电池性能.
- 开发稳定的SEI层对于推进电池技术至关重要.
研究的目的:
- 调查使用二 () 硫胺 (LiFSI) 作为 LiTPA 负电极的电解质盐.
- 通过形成高级SEI层来提高基于LiTPA的电池的循环性和速率性能.
- 了解负电极上的FSI-离子的电化学还原过程.
主要方法:
- 使用基于LiFSI的电解质对LiTPA电极进行电化学测试.
- 与含六酸 (LiPF6) 的参考电解质进行比较.
- 分析SEI层的组成和特性.
主要成果:
- 在LiTPA化之前,FSI-离子的电化学还原发生,形成了富含无机物的SEI层.
- 在SEI层中含有化 (LiF) 和硫酸 (Li2SO4).
- 与基于LiPF6的细胞相比,基于LiFSI的细胞显著改善了循环性能.
结论:
- 在LiTPA电极上,LiFSI有效地形成离子透性SEI层.
- 使用LiFSI可提高基于LiTPA的电池的循环性和速率性能.
- 这项研究提供了关于FSI- anion减排的见解,促进了可持续和高能耗电池的发展.
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