结构和表面工程促进商业碳布的离子储能能力
Qiyu Liu1,2, Wei Xu3, Dezhou Zheng3
1College of Chemistry and Material Engineering, Guiyang University, Guiyang 550005, People's Republic of China.
The Journal of chemical physics
|December 11, 2023
概括
研究人员为水性离子混合超级电容器开发了一种功能化的多孔碳布 (FPCC). 这种电极显著提高了容量和循环寿命,使高性能储能设备成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 水性离子混合超级电容器 (AZHSCs) 提供了高能量和功率密度的有希望的组合.
- 目前的AZHSC受到传统碳阴极容量较低的限制.
- 开发先进的阴极材料对于提高AZHSC性能至关重要.
研究的目的:
- 设计一个功能化的多孔碳布 (FPCC) 电极,以提高AZHSC性能.
- 研究有助于改善电化学性能的结构和表面修改.
- 展示FPCC在高性能准固态AZHSC中的潜力.
主要方法:
- 商业碳布 (CC) 通过结构和表面工程进行了修改,以创建FPCC.
- 评估了电化学性能,包括容量,循环寿命,能量密度和功率密度.
- 一个使用FPCC电极的准固态AZHSC装置被组装和测试.
主要成果:
- FPCC电极表现出显著增强的容量 (0.16 mAh cm-2在4 mA cm-2),比CC增加了923.8倍.
- 实现了特殊的循环稳定性,在3万个循环后保持了85.0%的容量.
- 该Zn//FPCC AZHSC显示出优越的能量 (3.3 mWh cm-3) 和功率密度 (240 mW cm-3).
结论:
- 功能化的多孔碳层和FPCC的充电接口增强了电气双层和伪电容.
- 开发的FPCC电极为AZHSC中碳阴极的容量限制提供了可行的解决方案.
- 这种修改策略为下一代高性能水性离子混合超级电容器铺平了道路.
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