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Updated: Jul 8, 2025

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在原子精确的银集群组装材料中单元-三元差距的调制

Priyanka Chandrashekar1, Gopa Sardar2, Turbasu Sengupta3

  • 1School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, Kerala, 695551, India.

Angewandte Chemie (International ed. in English)
|December 11, 2023
PubMed
概括

研究人员通过控制它们的分子包装来调整银色集群发光. 不同的连接物产生了不同的银 (Ag12) 集群组件,影响了它们的光物理性质,并为光电子材料提供了新的工具包.

关键词:
集群组装材料 集群组装材料纳米集群的纳米集群是什么?光是一种光.银色星团 银色星团 银色星团热激活的光体 热激活的光体

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Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
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